Syntax:
ALTER [IGNORE] TABLE tbl_name
    alter_specification [, alter_specification] ...

alter_specification:
    table_option ...
  | ADD [COLUMN] column_definition [FIRST | AFTER col_name ]
  | ADD [COLUMN] (column_definition,...)
  | ADD {INDEX|KEY} [index_name] [index_type] (index_col_name,...)
  | ADD [CONSTRAINT [symbol]]
        PRIMARY KEY [index_type] (index_col_name,...)
  | ADD [CONSTRAINT [symbol]]
        UNIQUE [INDEX|KEY] [index_name] [index_type] (index_col_name,...)
  | ADD [FULLTEXT|SPATIAL] [INDEX|KEY] [index_name] (index_col_name,...)
  | ADD [CONSTRAINT [symbol]]
        FOREIGN KEY [index_name] (index_col_name,...)
        [reference_definition]
  | ALTER [COLUMN] col_name {SET DEFAULT literal | DROP DEFAULT}
  | CHANGE [COLUMN] old_col_name column_definition
        [FIRST|AFTER col_name]
  | MODIFY [COLUMN] column_definition [FIRST | AFTER col_name]
  | DROP [COLUMN] col_name
  | DROP PRIMARY KEY
  | DROP {INDEX|KEY} index_name
  | DROP FOREIGN KEY fk_symbol
  | DISABLE KEYS
  | ENABLE KEYS
  | RENAME [TO] new_tbl_name
  | ORDER BY col_name [, col_name] ...
  | CONVERT TO CHARACTER SET charset_name [COLLATE collation_name]
  | [DEFAULT] CHARACTER SET charset_name [COLLATE collation_name]
  | DISCARD TABLESPACE
  | IMPORT TABLESPACE

index_col_name:
    col_name [(length)] [ASC | DESC]

index_type:
    USING {BTREE | HASH}

ALTER TABLE enables you to change the structure of an existing table.
For example, you can add or delete columns, create or destroy indexes,
change the type of existing columns, or rename columns or the table
itself. You can also change the comment for the table and type of the
table.

URL: http://dev.mysql.com/doc/refman/5.0/en/alter-table.html

